If you are just getting into .NET and specifically ASP.NET, then the following (2) MSDN Webcasts would be worth attending. They are free, so search and check the site often for other topics that interest you as well. The (2) below are level 200 webcasts that are geared for new ASP.NET developers.
MSDN Webcast: ASP.NET 4.0 Soup to Nuts (Part 1): Introduction to ASP.NET (Level 200)
MSDN Webcast: ASP.NET 4.0 Soup to Nuts (Part 2): Website Basics (Level 200)